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Met

h

anol O

p

erations

BOS-

P

RD-2

6

.900

6

09

4 D

escri

p

tion

T

he

fo

ll

ow

i

n

g

e

l

ements

of

th

i

s

sect

i

on

shall

be

ta

k

en

i

n

cons

i

derat

i

on when

deve

l

op

i

n

g

the

operat

i

on

and

the

spec

i

f

i

c methano

l

manua

l

s

.

4

.1

K

no

w

le

dg

e o

f

t

h

e

m

aterials

u

se

d

4

.1.1 W

h

at is Met

h

anol?

D

er

i

ved

from

natura

l

g

as

,

methano

l i

s

a

hydrocarbon

,

compr

i

sed

of

carbon

,

hydro

g

en

and

o

x

y

g

en

. I

ts

chem

i

ca

l

formu

l

a

i

s C

H

3

O

H

.

Methano

l i

s

an

a

l

coho

l

and

i

s

co

l

our

l

ess

,

neutra

l,

po

l

ar

and

f

l

ammab

l

e

liq

u

i

d

. I

t

i

s m

i

sc

i

b

l

e w

i

th water

,

a

l

coho

l

s

,

and most other

or

g

an

i

c

so

l

vents

. I

t

i

s

on

l

y

s

li

g

ht

l

y

so

l

ub

l

e

i

n

fats

and o

il

s

.

O

ther

common

names

for methano

l i

nc

l

ude methy

l

a

l

coho

l,

methy

l

hydrate

,

wood

sp

i

r

i

t

,

wood

a

l

coho

l

and

methy

l

hydro

xi

de

.

U

N

number

i

s

1

2

3

0 (S

ee

“

M

SDS

Methane

x”).

At

a

ll

sta

g

es

of

transport methano

l

shall

be

stored

secure

l

y

and

hand

l

ed respons

i

b

l

y

. T

h

i

s m

i

n

i

m

i

z

es

r

i

s

k

to

peop

l

e

and

the

env

i

ronment

,

and preserves

product

q

ua

li

ty

.

4.1.1.1 Overriding considerations

x

Methano

l i

s

an

eas

il

y

i

g

n

i

ted hydrocarbon

that burns

i

n

a

i

r

;

x

T

he mo

l

ecu

l

ar we

i

g

ht

of methano

l

vapor

i

s mar

g

i

na

ll

y

g

reater

(

denser

)

than

a

i

r

(

3

2

versus

28

g

rams

per mo

l

e

).

As

a

resu

l

t

,

and

depend

i

n

g

on

the

c

i

rcumstances

of

a

re

l

ease

,

methano

l

vapor may co

ll

ect

i

n

conf

i

ned

spaces

and

l

ow

-l

y

i

n

g

areas

;

x

I

n

certa

i

n

spec

i

f

i

c

c

i

rcumstances

,

methano

l

vapor

e

x

p

l

odes

on

i

g

n

i

t

i

on

;

x

Methano

l i

s

a

to

xi

n

; i

n

g

est

i

on

of

a

sma

ll

amount

(

between

one

and

two

ounces

,

appro

xi

mate

l

y

3

0

to

6

0

m

illili

ters

)

can

cause

death

; l

esser

amounts

are

k

nown

to

cause

i

rrevers

i

b

l

e

b

li

ndness

. D

o

not

eat

i

t

,

dr

i

n

k i

t

,

breathe

i

t

,

or

stand over

i

t

;

x

Methano

l i

s

tota

ll

y m

i

sc

i

b

l

e

i

n

water

.

A

7

5

%

water

and

2

5

%

methano

l

so

l

ut

i

on

i

s

cons

i

dered

to

be

f

l

ammab

l

e

liq

u

i

d

. T

h

i

s

has

i

mportant

i

mp

li

cat

i

ons

for

f

i

re

f

i

g

ht

i

n

g

.

4.1.1.2 Special provisions and protective measures

x

S

o

far

as

poss

i

b

l

e

,

methano

l

shall

be

stored

and

used

i

n

a

ded

i

cated

area that

i

s

spec

i

f

i

ca

ll

y mar

k

ed

off

and

appropr

i

ate

l

y

l

abe

l

ed

. T

h

i

s

area

shall

have

safety measures

read

il

y

ava

il

ab

l

e

to

emp

l

oyees

wor

ki

n

g

i

n

the

area

;

x

U

se pos

i

t

i

ve mater

i

a

l

s

i

dent

i

f

i

cat

i

on

for

g

as

k

ets

,

f

il

ters

,

hose mater

i

a

l,

etc

;

x

Ensure

procedures

are

i

n p

l

ace

to

g

round

,

and per

i

od

i

ca

ll

y

ver

i

fy

g

round

i

n

g

;

x

Ensure

procedures

are

i

n p

l

ace

to protect

from water

up

-

ta

k

e and accumu

l

at

i

on

;

x

Ensure

procedures

and

prov

i

s

i

ons

are

i

n

p

l

ace

for

prevent

i

n

g

methano

l

entry

i

nto the water

tab

l

e

or

a

q

u

i

fers

;

x

Ensure

procedures and

e

q

u

i

pment are

i

n

p

l

ace for

personne

l

protect

i

on

;

x

Ensure

procedures

and

e

q

u

i

pment are

i

n

p

l

ace

for

l

ea

k

detect

i

on

and

a

l

arm

;

x

Ensure

procedures

and

e

q

u

i

pment are

i

n

p

l

ace

for

ons

i

te emer

g

ency

response

;

x

Ensure

procedures

and

poss

i

b

l

y

spec

i

a

li

z

ed

e

q

u

i

pment

are

i

n

p

l

ace

for

offs

i

te

emer

g

ency

responders

;

x

E

l

ectr

i

ca

l

e

q

u

i

pment

shall

be e

x

p

l

os

i

on

-

proof

;

x

P

os

i

t

i

ve pressure may be

re

q

u

i

red

to ensure

that methano

l-

free areas

are

protected

;

x

G

round

i

n

g

i

s

espec

i

a

ll

y

i

mportant

i

n

protect

i

n

g

methano

l

from

acc

i

denta

l i

g

n

i

t

i

on

resu

l

t

i

n

g

from

stat

i

c

d

i

schar

g

e

;

V

ers

i

on

S

F

(BOS-

P

RD-07.900

6

09-

ver

.0

4

). O

r

i

g

i

na

l

date

: 22/0

6

/20

1

2.

V

ers

i

on

date

:

3

1

/

1

2/20

15

.

V

a

li

d

vers

i

on

on

l

y

on

Q

M

S

s

i

te

.

U

ncontro

ll

ed

document

when

pr

i

nted

.

P

rocedure prepared by

: BOS

H

ead

of

O

perat

i

ons

.

Approved

by

: BOS

H

ead

of

O

perat

i

ons

.

V

a

li

dated by

: BOS

Q

ua

li

ty

R

epresentat

i

ve

.

5

/

15

495